Still doesn't look right. Esp the head. I'll try to make a 3d sculpt of the head to show you what I kinda want. I'm not good at sculpting without an ortho or base model though...

She'll look way more demon-like than human like if anything, but in a cute way. Like Midna.

EDIT: Honestly move the eyes down, make them bigger, and that should fix that. There is wayyy too much 'empty space' there. Dress isn't what I've got in mind either, but thats MUCH easier to sculpt than a head.