I wanna say Erik Larsen was the first artist to change the blue in the classic Spidey costume to black... or at least made it a darker, near black...

[hider][img]http://www.comicsrecommended.com/images/fourteen/spider-man-amazing-338-red-black.jpg[/img]
[img]http://24.media.tumblr.com/b5fa3dc9883094b44384c359df6ea0dc/tumblr_mhe9izKvRH1qhpx4lo1_500.jpg[/img][/hider]